The formation of gypsum, from concentrated aqueous solutions of calcium sulphate, was so far thought to be a simple, single-step process. However, an international group of geochemists has now shown that gypsum forms through a complex four-step process.
The work done in understanding of this process opens the way to more energy-efficient production of plaster. It was published in the journal Nature Communications.
The international team from European Association Of Geochemistry examined the process and identified and quantified each of the steps of the formation process, highlighting specially that the initial moments in the reaction chain are of particular importance, because they determine the final properties of gypsum.
In the first step, tiny sub-3 nm elongated particles form the primary building blocks (bricks). In subsequent steps these bricks aggregate, self-assemble and rearrange themselves, and finally transform to gypsum crystals.
“Importantly, we envisage that it is possible to alter this pathway by specifically targeting individual stages. For example, we could arrest the reaction at the first stage when only nano-bricks are formed, and thus directly synthesise a highly reactive precursor to Plaster of Paris,” lead author of the study Thomas Stawsky said.
Senior author of the study, Liane G. Benning, who is the president of the European Association of Geochemistry, said: “We know that gypsum is naturally found on Mars, so applying our current finding will also help us understand and predict the hydrological conditions at the time of gypsum formation on other planets.”